Suzuki-Miyaura synthesis of biaryls

Methods for performing the Suzuki-Miyaura synthesis of biaryls 

Beside the already presented method based on Pd(OAc)2-catalysis (Table 3), the SM reactions with aryldiazonium salts can be alternatively accomplished in the presence of palladium(0)-stabilizing ligand, in situ generated from 255, to afford a wide variety of 

The SM reaction involving the aryldiazonium salts must include a rapid formation of an arylpalladium(II) intermediate from diazonium salt (evolution of nitrogen oceurs) 

Aryl iodides and bromides are the most commonly employed Suzuki-Miyaura electrophilic counterparts [1-9]. The SM methodology for aryl iodides and bromides is presented in the Tables 4 and 5. 

Beside PPhj, other bidentate diphosphines, e.g. dppf, can be employed. 

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