Surrounding, effect

In order to study means of suppressing shock-wave luminosity in the ambient medium, tests were made with Tetryl chges of d s 1.4 1.6g/cc surrounded by air, propane and water. The F igs 2 3 of the Oct-Dec 1952 rept showed that propane and water surrounds effectively eliminated the shock wave luminosity (Figs are not shown here)... 

If hydrodynamics and related mass transfer kinetics mainly control the first two, thermodynamic equilibrium cilso plays a main part in the third. The occurrence of secondary phenomena, such as solute modifications due to surrounding effects, must also be mentioned due to possible induced interferences. 

An introduction of the surrounding effects for very ionic materials, like MgO, is in principle, relatively easy. The main term here is the inclusion of... 

Very T, Despax S, Hebraud P, Monari A, Assfeld X (2012) Spectral properties of polypyridyl ruthenium complex intercalated in DNA theoretical insights on the surrounding effects for [Ru(dppz)(bpy)j2+. phys Chem Chem Phys 14 12496-12504... 

Chantzis A, Very T, Monari A, Assfeld X (2012) Improved treatment of surrounding effects UV/vis absorption properties of a solvated Ru(II) complex. J Chem Theory Comp 8 1536... 

Finally, Section 8.3.3 reports the theoretical study of the second-order nonUnear optical properties of the anil crystals 10 and 12, as well as the optical contrasts upon switching between their enol (E) and keto (K) forms. The calculations demonstrate that crystal packing impacts the K/E optical contrasts in the two systems differently, which illustrates the importance of the supramolec-ular organization on the macroscopic responses. In 10, the surrounding effects on the (hyper)polarizabihties are similar in the enol and keto forms, leading to optical contrasts very close to those of the isolated molecule. On the contrary, an enhancement of the second-order susceptibility is observed in the keto form of 12, leading to a large contrast. Moreover, the / (10)/,[ < (12) ratio... 

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