Supporting Data and Implications

The structure along the pseudo twofold axis bisecting the P(l)—Rh—P(2) angle (the binaphthyl group is not depicted)  

SCHEME 17. Molecular structure of [Rh((/f)-binap)(nbd)] C104. LA. Miyashita, A. Yasuda, H. Takaya, T. Ito, T. Souchi, and R. Noyori, J. Am. Chem. Soc., 102, 7932 (1980) K. Toriumi, T. Ito, H. Takaya, T. Souchi, and R. Noyori, Acia Crysi., B38, 807 (1982) R. Noyori and H. Takaya, Chemica Scripta, 25, 83 (1985). Reproduced by permission of the American Chemical Society and the Royal Swediah Academy of Sciences.  

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