Supplement to Chapter

Supplement to Chapter 6.3 Hydrosilylation of Carbonyl and Imino Groups... 

As a final part of this chapter, we shall briefly discuss the intramolecular ET processes in relatively large aromatic molecules. This is a supplement to Chapter 3 in this Part, in which twisted intramolecular charge-transfer (TICT) phenomena were described for isolated donor acceptor molecules and their clusters. Here we present the charge-transfer dynamics in some selected anthryl derivatives in which the donor and acceptor parts are linked directly or by alkyl chains, and also microscopic solvation effects on the dynamic properties in their clusters, which were not discussed in the earlier chapter. The emphasis resides on a detailed description of the torsional motions and the solvation structure, which are strongly correlated with the intramolecular charge transfer in these systems. 

Another approach that can be used to calculate intermolecular interaction energies is the PIXEL method, which has been apphed extensively to organic crystals. In principle, it can also be applied to molecular inorganic crystals. The interested reader is referred to the pixel section of the on-line supplement to Chapter 3 for further information. 

Information about nuclear spins is given in Table 4.1. For a set of worked examples on various aspects of NMR spectroscopy see the on-line supplement to Chapter 4. 

Other methods used to get rotational data from electronic and vibrational spectra, including doubleresonance methods, are described in the on-line supplement to Chapter 7. 

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