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A detailed study of the mechanism of the allyl sulphoxide-sulphenate rearrangement and its uses in synthesis has been reported. Rates of steroidal allyl sulphoxide rearrangements are influenced by chirality at sulphur, and configurational aspects established for compounds of this... [Pg.46]

See other pages where Sulphenates chiral is mentioned: [Pg.1197] [Pg.1204] [Pg.225] [Pg.232] [Pg.65] [Pg.160] [Pg.162] [Pg.44] [Pg.75]