Sulfuryl chloride alkane chlorosulfonation

Alkanes can be simultaneously chlorinated and chlorosulfonated. This commercially useful reaction has been applied to polyethylene (201—203). Aromatics can be chlorinated on the ring, and in the presence of a free-radical initiator alkylaromatic compounds can be chlorinated selectively in the side chain Ring chlorination can be selective. A patent shows chlorination of 2,5-di- to 2,4,5-trichlorophenoxyacetic acid free of the toxic tetrachlorodibenzodioxins (204). With alkenes, depending on conditions, the chlorination can be additive or substitutive. The addition of sulfuryl chloride can occur to form a 2-chloroalkanesulfonyl chloride (205). 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ , ]

See also in sourсe #XX -- [ ]

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