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Sulfoxidation of Alkanes Catalyzed by Vanadium

The sulfoxidation of aromatic hydrocarbons has been extensively studied, but work on the sulfoxidation of saturated hydrocarbons to alkanesulfonic acids remains at a less satisfactory level. The Strecker reaction using alkyl halides, preferably alkyl bromides, and alkali metal or ammonium sulfides, is commonly used for the synthesis of alkanesulfonic adds [153]. Another procedure, the oxidation of thiols with bromine in the presence of water or hydrogen peroxide and acetic acid, has been [Pg.214]

NHPI/V0(ac3ic 0S% CDnv 6S%) VO(acac t (Cqhm. 435b) [Pg.215]

The sulfoxidation may be initiated by one-electron transfer from an alkane to a V(V) species generated in situ from VO(acac)2 and O2 to form an alkyl cation radical which [Pg.215]


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Alkanes sulfoxidation

Vanadium-catalyzed

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