Sulfido

Salts are formed as with oxygen-containing compounds. For example, C2H5 — S—Na is named either sodium ethanethiolate or sodium ethyl sulfide. If mercapto- has been used as a prefix, the salt is named by use of the prefix sulfido- for —S . 

Monomeric sulfur diimides have an extensive coordination chemistry as might be anticipated from the availability of three potential donor sites and two r-bonds. In addition, they are prone to fragmentation to produce thionitroso and, subsequently, sulfido and imido ligands. Under mild conditions with suitable coordinatively unsaturated metal... 

Another remarkable reaction is the nucleophilic substitution of the chlorine by alkoxy or sulfido groups using the alcohol or the thiol and the weak base Na2C03 in situ. For example, in the case of ethanol, the reaction proceeds in 12 h at reflux Eq. (23), Table 3. 

Interesting new sulfido complexes of tin have been prepared by the reaction of styrene sulfide with the N-alkylated tin(II) amidinate complexes Sn[RC(NCy)2]2 (Cy = cyclohexyl R = Me, Bu ). The products exhibit two very different bonding modes for the sulfido ligands in one case, S = Sn[RC(NCy)2]2/ a terminal Sn = S moiety was found while in the other case the bridging... 

The reaction of [p-MeC6H4C(NSiMe3)2]2Ta( = CH2)CH3 with 2,6-dimethyl-phenyl isocyanide afforded an f/ -ketenimine complex (Scheme 118). Carbon-sulfur cleavage reactions produced tantalum thioformaldehyde and tantalum sulfido complexes. ... 

Cubane and Incomplete Cubane-Type Molybdenum Emd Tungsten Oxo/ Sulfido Clusters Takashi Shihahara... 

Fici. 80. Electrocheinical behavior of a sulfido diniolyhdenuiTi-dicobalt cluster X = MoiCosl/t-i-S K/<. 1-8 )2(CO )4( HaMe) I... 

Complexes with sulfido and monodentate thiol ligands 322... 

---