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Sulfides vinyl, reaction with Grignard

Aromatic and vinylic sulfides take part in cross-coupling reactions with Grignard reagents in the presence of Ni catalysts.336,337 This reaction has been applied to the enantioselective synthesis of binaphthyls using a standard chiral oxazoline ligand (Equation (25)) 338... [Pg.339]

The nickel-catalysed reaction of aryl, allyl or vinyl sulfides with Grignard reagents has been found to be an effective way for the conversion of carbon-sulfur bonds into carbon-carbon bonds [318]. However, simple aliphatic substrates are inert. [Pg.53]

See other pages where Sulfides vinyl, reaction with Grignard is mentioned: [Pg.130] [Pg.84] [Pg.1683] [Pg.153] [Pg.27] [Pg.214] [Pg.214] [Pg.385] [Pg.493] [Pg.847] [Pg.258] [Pg.1125] [Pg.467] [Pg.795] [Pg.803] [Pg.214] [Pg.237] [Pg.795] [Pg.362] [Pg.120] [Pg.230] [Pg.492] [Pg.375] [Pg.651] [Pg.236] [Pg.51]

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Reaction with sulfides

Sulfides, vinyl reaction with Grignard reagents

Vinyl Grignard

Vinyl reaction

Vinyl sulfides

Vinylic sulfides