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Sulfides, trimethylsilyl alkyl regioselectivity

Trimethylsilyl alkyl and aryl sulfides react with allyl carbonates and vinyl epoxides to deliver the alkyl or aryl sulfide to the allyl unit. These species show typical regioselectivities by (i) adding to the less substituted end of alkyl substituted allyls (equation 290) (ii) adding to the allyl terminus more distant from remote oxygen functionality (equation 291) and (iii) showing substantial endocyclic addition to methylenecyclohexane-derived allyls (equation 292).223... [Pg.642]

See other pages where Sulfides, trimethylsilyl alkyl regioselectivity is mentioned: [Pg.434]   
See also in sourсe #XX -- [ Pg.642 ]

See also in sourсe #XX -- [ Pg.4 , Pg.642 ]

See also in sourсe #XX -- [ Pg.4 , Pg.642 ]



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Alkyl sulfides

Alkylation regioselectivity

Sulfides alkylated

Sulfides alkylation

Sulfides, trimethylsilyl alkyl

Trimethylsilyl sulfides

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