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Sucrose conformational analysis

Lemieux, R U, Huber, G, A chemical synthesis of sucrose. A conformational analysis of the reactions of 1,2-anhydro-a-D-glucopyranose triacetate, J. Am. Chem. Soc., 78, 4117-4119, 1956. [Pg.190]

The structure, conformation and intramolecular hydrogen bonds of crystalline and aqueous sucrose have been discussed in detail. Evidence for a transient inter-residue hydrogen bond in aqueous sucrose (0-2- -H O-T) has been discovered by ROESY spectroscopy imder supercooled conditions.Combined use of high resolution NMR techniques and dynamics simulations furnished a new model for the dynamical conformational behaviour of sucrose in water in which internal motions occur at the same rate as overall tumbling. A GROMOS force field analysis, modified to include a potential energy term for the fxo-anomeric effect, has been assessed for efficiency by application to a conformational analysis of a-maltose. ... [Pg.321]

See other pages where Sucrose conformational analysis is mentioned: [Pg.16]    [Pg.168]    [Pg.132]    [Pg.30]    [Pg.203]    [Pg.60]    [Pg.1]    [Pg.10]    [Pg.216]    [Pg.10]    [Pg.16]    [Pg.456]    [Pg.247]    [Pg.265]    [Pg.356]    [Pg.253]    [Pg.5]    [Pg.190]    [Pg.172]    [Pg.101]    [Pg.248]    [Pg.309]    [Pg.12]    [Pg.14]    [Pg.51]    [Pg.140]    [Pg.549]    [Pg.58]    [Pg.16]    [Pg.229]    [Pg.286]    [Pg.293]    [Pg.2611]    [Pg.129]   
See also in sourсe #XX -- [ Pg.214 ]



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Conformation analysis

Conformational analysis

Sucrose analysis

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