Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Substrate bridge complexes formation mechanism

Binuclear zinc complexes wherein each metal center is supported by a tripodal tetradentate ligand environment involving a bridging phenolate donor are reactive toward tris(4-nitrophenyl) phosphate and bis(4-nitrophenyl) phosphate in ethanol/ water.234 The pH-rate profile studies of these reactions are consistent with a mechanism that involves the formation of a reactive mononuclear zinc hydroxide species via cleavage of the binuclear solid-state structure. This mononuclear Zn-OH species is proposed to act as the nucleophile toward the phosphate ester substrate. [Pg.147]

See other pages where Substrate bridge complexes formation mechanism is mentioned: [Pg.14]    [Pg.36]    [Pg.13]    [Pg.220]    [Pg.395]    [Pg.52]    [Pg.105]    [Pg.49]    [Pg.525]    [Pg.220]    [Pg.220]    [Pg.410]    [Pg.37]    [Pg.250]    [Pg.360]    [Pg.344]    [Pg.258]    [Pg.167]    [Pg.396]    [Pg.224]    [Pg.457]    [Pg.718]    [Pg.167]    [Pg.64]    [Pg.123]    [Pg.124]    [Pg.300]    [Pg.197]    [Pg.211]    [Pg.532]    [Pg.1403]    [Pg.167]    [Pg.16]    [Pg.64]    [Pg.562]    [Pg.1194]    [Pg.173]    [Pg.669]    [Pg.152]    [Pg.388]    [Pg.312]    [Pg.190]    [Pg.48]    [Pg.53]    [Pg.92]    [Pg.90]    [Pg.171]    [Pg.14]    [Pg.351]    [Pg.1672]   
See also in sourсe #XX -- [ Pg.481 , Pg.482 ]

See also in sourсe #XX -- [ Pg.481 , Pg.482 ]



SEARCH



Bridging mechanism

Mechanism complex formation

Mechanism complexes

Substrate bridge complexes

Substrate complex

Substrate mechanisms

© 2024 chempedia.info