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Substituted Triorganogermanium Oxides and Hydroxides

Bischloromethyldimethylgermanium Oxide (M-101) GeaCeHxeClaO (Me2GeCHaCl)20 Synth. By hydrolysis of Me2(ClCH2)GeCl with aq. NaOH in EtaO (21314-), in 88% yield (215U), of [Me2(ClCH2)Ge]2NH (2134). [Pg.162]

t By rxn. of 2-(Me2GeCl)2C2BioHio with H2O in Me2C0, in quant, yield (1835)  [Pg.162]

5-digerma-2,5-dihydrofurane Synth. By-prod, in rxn. of I with excess (Me02CC )2 [Pg.162]

By rxn. of ferrocene with (Me2N 4Ge and cat. AICI3, followed by H2O, in 25 0 yield (1952), with (Me2N)2GeCl2 in below 1% yield (1952). [Pg.163]

Additional functionally substituted triorganogermaniiam oxides and hydroxides are listed at the bottom of Table [Pg.163]


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Oxidative substitution

Oxide-hydroxides

Oxides and Oxide-hydroxides

Oxides and hydroxides

Substituted Oxidation

Triorganogermanium Oxides and Hydroxides

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