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Structural information from valence-shell PE spectroscopy making assignments

3 Structural information from valence-shell PE spectroscopy making assignments [Pg.285]

The photoelectron spectrum of a molecule is closely related to the set of occupied valence orbitals. For simple molecules, some PE bands show discrete structure due to vibrational excitation of the ion this can be interpreted in terms both of the bonding/non-bonding/anti-bonding character of the electron removed and of the vibration frequencies of the ion, as described in the last section. All of this information is related to [Pg.285]

He(I) photoelectron spectrum of HCl. Redrawn from [6]. Copyright 1970 John Wiley Sons. [Pg.286]




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Information from

PES Spectroscopy

Shell structure

Spectroscopy structure)

Spectroscopy valence

Structural assignments

Structural information

Structural information structure

Structure information

Structure making

Structure valency

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