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Strong field configuration Alternate

The approach we have adopted for the d configuration began from the so-called strong-field limit. This is to be contrasted to the weak-field scheme that we describe in Section 3.7. In the strong-field approach, we consider the crystal-field splitting of the d orbitals first, and then recognize the effects of interelectron repulsion. The opposite order is adopted in the weak-field scheme. Before studying this alternative approach, however, we must review a little of the theory of free-ion spectroscopy... [Pg.39]

Table 13.1 Crystal field stabilization energies for weak field and intermediate field octahedral complexes. Where alternative configurations are given, the fractional values are the weak-field limit and the integer values are the strong-field limit (between them they give the intermediate field range)... Table 13.1 Crystal field stabilization energies for weak field and intermediate field octahedral complexes. Where alternative configurations are given, the fractional values are the weak-field limit and the integer values are the strong-field limit (between them they give the intermediate field range)...

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Alternating fields

Alternative configuration

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