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Strained ring-tilted metallocenophanes bridge

The first examples of the use of ROP of strained metallocenophanes to prepare high molecular weight polymetallocenes (Mn>10 ) involved silicon-bridged [Ijferrocenophane monomers 3.21 [61]. Specifically, polyferrocenylsilanes (PFSs) 3.22 (R,R = Me or Ph) were prepared by the thermal ROP of strained, ring-tilted silicon-bridged [l]ferrocenophanes 3.21 (R,R = Me or Ph) in the melt, at 130-... [Pg.82]

See other pages where Strained ring-tilted metallocenophanes bridge is mentioned: [Pg.133]    [Pg.323]    [Pg.442]    [Pg.164]    [Pg.221]    [Pg.156]    [Pg.160]    [Pg.325]   
See also in sourсe #XX -- [ Pg.453 ]



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Bridged rings

Metallocenophane

Metallocenophanes

Ring strain

Ring strain, metallocenophanes

Ring tilting

Ring tilts

Strained metallocenophanes

Strained ring-tilted metallocenophanes

Strained rings

TILT

Tilting

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