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Strain and reactivity

Steric strain and reactivity of 3-oxatricyclo[3.2.1.0 " ]octanes (epoxynorbor-nanes) 99ZOR661. [Pg.243]

Molecular Basis of Mechanochemical Degradation 3.1 Molecular Strain and Reactivity... [Pg.102]

The highly strained and reactive 2iT-azirines have been extensively studied for various synthetic purposes, such as ring expansion reactions, cycloaddition reactions, preparation of functionalized amines and substituted aziridines. The older literature on azirines in synthesis has extensively been reviewed [69]. Concerning azirines with defined chirality only scarce information is available. Practically all reactions of azirines take place at the activated imine bond. Reduction with sodium borohydride leads to cz5-substituted aziridines as is shown in Scheme 48 [26,28]. [Pg.121]

Trost, B. M. Strain and Reactivity Partners for Delective Synthesis. 133, 3-82 (1986). [Pg.186]

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See also in sourсe #XX -- [ Pg.1085 ]



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