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Stochastic reaction kinetics nonequilibrium thermodynamics of state-space

1 Stochastic reaction kinetics nonequilibrium thermodynamics of state-space 7 [Pg.115]

Our starting point is the Kramers-Moyal-Stratonovich equation (5.13). Neglecting the higher-than-first-order conditional moments the drift equation is obtained  [Pg.115]

Since g is a probability density function, and a deterministic initial condition has been assumed, the following conditions hold  [Pg.115]

The unique solution of (5.67) satisfying the condition (5.68) is the 5, ) distribution, where x t) is the solution of the initial value problem [Pg.115]

The statement can be proved by solving (5.67) for the function g( ), and taking into consideration the condition (5.68). The theoretical basis of the procedure can be found in Hormander (1964), and the statement may be interpreted in four different ways. [Pg.115]




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Kinetic space

Kinetic/thermodynamic

Nonequilibrium

Nonequilibrium reactions

Nonequilibrium thermodynamics

Reaction space

Reactions thermodynamics

Space of states

State, thermodynamic

State-space

Stochastic thermodynamics

Thermodynamic reactions

Thermodynamics of reactions

Thermodynamics, kinetics

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