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Steroid Side Chain Homologation

Ketones can be homologated to unsaturated ketones or aldehydes by addition of the appropriate vinyl nucleophile followed by oxidative rearrangement, as shown in Scheme 9. The use of this traiisformation in a synthetic approach to steroids with unsaturated side chains is shown in equation (16). ... [Pg.821]

See other pages where Steroid Side Chain Homologation is mentioned: [Pg.189]    [Pg.189]    [Pg.828]    [Pg.828]    [Pg.779]    [Pg.780]    [Pg.210]    [Pg.828]    [Pg.381]    [Pg.37]    [Pg.377]    [Pg.359]    [Pg.192]    [Pg.785]    [Pg.621]   


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Steroidal side chains

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