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Stereoselective palladation

Stoichiometric palladation of the allylsilane (R)-5 leads stereoselectively to the re-allyl complex (1 of 85% op containing a re-allyl moiety as the sole stereogenic element14. Anima-... [Pg.1148]

Indenols, and ultimately indanones, can be prepared via a nucleophilic vinyl pallad-ation of o-bromobenzaldehyde. Stereoselective addition of a -amino-organometallics to aldehydes have been reviewed (62 references). " Diastereoselective additions of MeMgX and MeLi to an oxo-sugar have been reported. ... [Pg.28]


See other pages where Stereoselective palladation is mentioned: [Pg.196]    [Pg.196]    [Pg.196]    [Pg.196]    [Pg.95]    [Pg.155]    [Pg.335]    [Pg.632]    [Pg.226]    [Pg.443]    [Pg.288]    [Pg.148]    [Pg.632]    [Pg.94]    [Pg.82]    [Pg.258]   
See also in sourсe #XX -- [ Pg.195 , Pg.205 , Pg.207 ]

See also in sourсe #XX -- [ Pg.195 , Pg.205 , Pg.207 ]




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Palladation

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