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Step function stoichiometric range

The number of independent equilibrium relationships among the partial mole numbers, N, is equal to the number of independent steps in the fast equimolecular mechanism, which we call R. A ere changes in N are possible, R may not exceed (S — C — 1), where S is the total number of species being considered (the range of the index i), and C is the number of stoichiometric components of these species (the independent chemical elements). When R = S — C — 1), the composition to which the system tends through the fast reactions alone is a imique function of N, determined by the temperature and the initial composition. This function is conspicuously independent of density. [Pg.121]


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