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Statistics of SAWs in continuous space

Expressions (8.13)-(8.18) represent the SAW statistics at /-dimensional lattice. In a metric space, incorporating the variable of shifting the x,-semi-axis of conformational ellipsoid, with the states Mp(s) belonging to its surface [Pg.285]

Substitution of (8.19) induces an essential distinction between w(x) and ( 1 w(x) determines the probability (jc) that the SAW trajectory at given parameters TV and Oi will end in an elementary volume dx, laying on an ellipsoid surface with semi-axes jc i= i,d. In the other case, all the surface of ellipsoid is a geometrical place of points or chain end states with the same corresponding distribution density w(x). [Pg.286]

The maximum of w(jc) at given N and oj corresponds to the most probable or equilibrium state of a polymer chain. The semi-axes x of the equilibrium conformational ellipsoid can be found firom the condition [Pg.286]

We will continue to consider the situation when all the directions of chain steps are equiprobable, i.e  [Pg.286]

Substitution of (8.27) into (8.25) makes the semi-axes of equilibrium ellipsoid equal, and equal to the radius of the Flory ball [Pg.286]


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Continuous space

Saw, sawing

Sawing

Spacing—continued

Statistics continuous

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