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State correlation diagrams Dauben-Salem-Turro

The mechanism of photoenolization in 1-methylanthraquinone has been studied in detail (Gritsan, N. P. Khmelinski, I. V. Usov, . M., J. Am. Chem. Soc., 1991, 113, 9615). The reaction was found to occur in both the singlet and triplet (nn ) states. Develop a Dauben-Salem-Turro state correlation diagram for the photochemical step and, on the basis of your diagram, discuss the efficiency of the reaction... [Pg.300]

This question involves the analysis of carbonyl photochemistry using Dauben-Salem-Turro state correlation diagrams. [Pg.298]

The photochemistry of l,5-hexadien-3-ones has been examined by Dauben and coworkers. A relatively rare dependence of the intramolecular enone-olefin photoaddition of several derivatives has been observed. Discuss the mechanistic possibilities in terms of Dauben-Salem-Turro state correlation diagrams. (See Dauben, W. G. Cogen, J. M. Ganzer, G. A. Behar, V., J. Am. Chem. Soc., 1991, 113, 5817.)... [Pg.300]

In Chapter 15, the state correlation diagram approach of the previous chapter is applied to a brief discussion of photochemistry in the manner of Dauben, Salem, and Turro [13]. A more comprehensive approach to this subject may be found in the text by Michl and Bonacic-Koutecky [14], Turro [15], or Gilbert and Baggott [16]. [Pg.337]


See other pages where State correlation diagrams Dauben-Salem-Turro is mentioned: [Pg.214]    [Pg.217]    [Pg.298]    [Pg.298]    [Pg.299]    [Pg.300]    [Pg.301]    [Pg.214]    [Pg.217]    [Pg.298]    [Pg.299]    [Pg.300]    [Pg.301]    [Pg.78]    [Pg.214]    [Pg.217]    [Pg.298]    [Pg.298]    [Pg.299]    [Pg.300]    [Pg.301]    [Pg.214]    [Pg.217]    [Pg.298]    [Pg.298]    [Pg.299]    [Pg.301]    [Pg.107]    [Pg.107]   
See also in sourсe #XX -- [ Pg.212 ]

See also in sourсe #XX -- [ Pg.212 ]




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Correlation states

Salem

Salem diagram

State correlation diagram

Turro

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