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Persistent Stannylenes

Like the Sn(III) radicals, the Sn(II) stannylenes are familiar both as persistent species of unlimited life and as transient, highly reactive intermediates. Many of the compounds that, in the older literature, were... [Pg.26]

The first landmark syntheses of persistent radicals of the heavier group 14 elements were reported nearly 30 years ago by Lappert s group. ° The first radical of this series, [(Me3Si)2CH]3Sn , was prepared by photolysis of the stable stannylene [(Me3Si)2CH]2Sn with visible light in benzene (Scheme 2.26). ° =... [Pg.75]

See other pages where Persistent Stannylenes is mentioned: [Pg.864]    [Pg.866]    [Pg.698]    [Pg.336]    [Pg.353]    [Pg.9]    [Pg.163]   
See also in sourсe #XX -- [ Pg.353 ]



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Stannylene

Stannylenes

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