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Carbenes stable singlet

Since this discovery, a few types of other stable singlet carbenes have been described and reviewed5 imidazol-2-ylidenes,6 l,2,4-triazol-3-yli-denes,7 imidazolidin-2-ylidenes,8 acyclic diaminocarbenes,9 thiazol-2-yli-denes,10 and acyclic aminooxy- and aminothiocarbenes.11... [Pg.176]

Synthesis and Structural Data for Stable Singlet Carbenes. 335... [Pg.329]

Since this discovery, a few persistent triplet carbenes have been prepared and other types of stable singlet carbenes have been isolated. Triplet carbenes are discussed in Chapter 9 by H. Tomioka in this volume, and therefore this chapter will be focused on singlet carbenes. [Pg.330]

SYNTHESIS AND STRUCTURAL DATA FOR STABLE SINGLET CARBENES... [Pg.335]


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Amino groups stable singlet carbenes

Bond angle stable singlet carbenes

Carbenes stable

Cyclopropanation stable singlet carbenes

Diaminocarbenes stable singlet carbene

Diazo compounds stable singlet carbenes

Dimerization stable singlet carbenes

Imidazol-2-ylidenes, stable singlet carbenes

Reaction mechanisms stable singlet carbenes

Singlet carbene

Singlet carbenes

Stable singlet carbenes, electronically active

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