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Stabilities and reactivities of carbocations

A further dependence of the selectivity between different nucleophiles on the stability and reactivity of carbocations was found by Richard and Amyes in a study of reactions of alcohols and carboxylate anions with -substituted a-trifluoromethyl benzyl cations (75, X = Me, OMe, SMe, N(Me)CH2CF3, and NMe2) monitored using the azide clock.305 Apart from the methyl-substituted substrate, for which the reactions approached diffusion control,... [Pg.108]

See other pages where Stabilities and reactivities of carbocations is mentioned: [Pg.19] [Pg.19] [Pg.21] [Pg.23] [Pg.25] [Pg.27] [Pg.29] [Pg.31] [Pg.33] [Pg.35] [Pg.37] [Pg.39] [Pg.41] [Pg.43] [Pg.45] [Pg.47] [Pg.49] [Pg.51] [Pg.53] [Pg.55] [Pg.57] [Pg.59] [Pg.61] [Pg.63] [Pg.65] [Pg.67] [Pg.69] [Pg.71] [Pg.73] [Pg.75] [Pg.77] [Pg.79] [Pg.81] [Pg.83] [Pg.85] [Pg.87] [Pg.89] [Pg.91] [Pg.93] [Pg.95] [Pg.97] [Pg.99] [Pg.101] [Pg.103] [Pg.105] [Pg.107] [Pg.109] [Pg.111] [Pg.113] [Pg.115]

See also in sourсe #XX -- [ Pg.19 , Pg.44 ]

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And carbocations

Carbocation stability

Carbocation stabilization

Carbocations and stability

Carbocations reactivity

Carbocations stability

Carbocations stabilization

Carbocations stabilized

Of carbocations

Reactivities of carbocation

Stability of carbocations