Spin delocalization, polynuclear molecules

Spin-crossover, definition, 32 2 Spin delocalization, polynuclear molecules, 43 182-183... 

Ruthenium(III), d5 Ru111 is often associated with classical-type ligands, e.g. ammine, water, halides. They are octahedral low spin t2/ species with one unpaired electron and generally sub-stitutionally inert. The electronic structure of polynuclear carboxylates and mixed valence Ru" 1" complexes of the type [Ru(NH3)5]2L5+ has been the subject of much interest particularly with respect to the degree of unpaired electron delocalization within these molecules. 

---

See also in sourсe #XX -- [ ]

---