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Spectroscopy angular distortions

These phenomena can be reliably traced back to Jahn-Teller and strain distortion combined to unquenched orbital angular momentum due to spin-orbit-coupling in the metalloporphyrins. The Jahn-Teller distortion has been also studied by resonance Raman spectroscopy. " ... [Pg.95]

Centrifugal distortion - An effect in molecular spectroscopy in which rotational levels are lowered in energy, relative to the values of a rigid rotor, as the rotational angular momentum increases. The effect may be understood classically as a stretching of the bonds in the molecule as it rotates faster, thus increasing the moment of inertia. [Pg.99]

See other pages where Spectroscopy angular distortions is mentioned: [Pg.489]    [Pg.151]    [Pg.455]    [Pg.201]    [Pg.846]    [Pg.21]    [Pg.40]    [Pg.46]    [Pg.150]    [Pg.412]    [Pg.270]    [Pg.26]    [Pg.181]    [Pg.100]    [Pg.187]    [Pg.1182]    [Pg.26]    [Pg.95]   
See also in sourсe #XX -- [ Pg.237 ]



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Angular distortion

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