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Specific reactivity patterns

Olefin metathesis is one of the most important reaction in organic synthesis [44], Complexes of Ru are extremely useful for this transformation, especially so-called Grubbs catalysts. The introduction of NHCs in Ru metathesis catalysts a decade ago ( second generation Grubbs catalysts) resulted in enhanced activity and lifetime, hence overall improved catalytic performance [45, 46]. However, compared to the archetypal phosphine-based Ru metathesis catalyst 24 (Fig. 13.3), Ru-NHC complexes such as 25 display specific reactivity patterns and as a consequence, are prone to additional decomposition pathways as well as non NHC-specific pathways [47]. [Pg.308]

Specific Reactivity Patterns in Electron-Transfer Reactions... [Pg.116]

Specific Reactivity Patterns in Electron-Transfer Reactions 12.2.S.2. Variation with the Oxidant 12.2.5.2.1. One-Electron Oxidants... [Pg.130]

See other pages where Specific reactivity patterns is mentioned: [Pg.83]    [Pg.42]    [Pg.127]    [Pg.128]    [Pg.129]    [Pg.132]    [Pg.133]    [Pg.134]    [Pg.135]    [Pg.136]    [Pg.137]    [Pg.138]    [Pg.139]    [Pg.140]    [Pg.141]    [Pg.142]    [Pg.143]    [Pg.105]    [Pg.106]    [Pg.107]    [Pg.110]   


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Reactivity patterns

Specific reactivity patterns in electron-transfer reactions

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