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Solvolysis amido group

P. J. L. Daniels et synthesised 2 -epi-gentamicin Ci 225 and 2"-deoxy-gentamicin C2 226. Penta-N-acetylgentamicin Cj is mesylated at the 2 -hydroxyl group. Through solvolysis of the mesylate by participation of the vicinal trans acet-amido group, epimerisation at the 2"-C atom takes place. [Pg.149]

See other pages where Solvolysis amido group is mentioned: [Pg.133]    [Pg.186]    [Pg.303]    [Pg.601]    [Pg.206]    [Pg.320]    [Pg.175]    [Pg.335]    [Pg.45]   
See also in sourсe #XX -- [ Pg.305 ]



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