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Solvent effects cyano complexes

Stereochemical and kinetic studies of the stepwise aquation of the [Cr(CN)6] and [Cr(CN)5(NO)] anions have indicated that the cyano-ligand has a strong rranj -labilizing effect in this type of complex. Hence it seemed an attractive idea to study this postulated effect in the simplest member of this group, the [Cr(OH2)5(CN)] + cation. Unfortunately accurate kinetic studies of substitution reactions of this complex were ruled out by the observation that aquation and anation processes occur at comparable rates.The strong trans effect of iodide complexed to chromium(m) is mentioned in the section on mixed and non-aqueous solvents below. [Pg.198]

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See also in sourсe #XX -- [ Pg.217 , Pg.222 ]



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