Solutions frictional properties

We shall discuss three types of phenomena for polymer solutions thermodynamic properties in Chap. 8, frictional properties in Chap. 9, and lightscattering properties in Chap. 10. A common feature of virtually all phenomena in these areas is that they all depend on the molecular weight of the solute. Thus observations of these properties can be interpreted to yield values for M we shall use this capability as a unifying theme throughout these chapters. 

Most descriptions of the dynamics of molecular or particle motion in solution require a knowledge of the frictional properties of the system. This is especially true for polymer solutions, colloidal suspensions, molecular transport processes, and biomolecular conformational changes. Particle friction also plays an important role in the calculation of diffusion-influenced reaction rates, which will be discussed later. Solvent multiparticle collision dynamics, in conjunction with molecular dynamics of solute particles, provides a means to study such systems. In this section we show how the frictional properties and hydrodynamic interactions among solute or colloidal particles can be studied using hybrid MPC-MD schemes. 

It has been shown, by theories of the frictional properties of polymer molecules in solution, that the intrinsic viscosity is proportional to the effective hydrodynamic volume of the molecule in solution divided by its Molecular weight. The effective volume is proportional to the cube of a linear dimension... 

The analytical solutions derived in Sections 4.3 and 4.4 for the stress distributions in the monotonic fiber pull-out and fiber push-out loadings are further extended to cyclic loading (Zhou et al., 1993) and the progressive damage processes of the interface are characterized. It is assumed that the cyclic fatigue of uniform stress amplitude causes the frictional properties at the debonded interface to degrade... 

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