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Sodium Magnesiate Complexes

Donor-Free Homo- and Heteroleptic Sodium Magnesiate Complexes... [Pg.14]

The donor-firee sodium magnesiate complexes with general formula [Na4Mg2(TMP)6(arene-di-ide)] (arene-di-ide = 2,5-C6H30Me in 54 3,5-C6H3NMe2 in 55 and 3,5-C6H3Me in 56 Fig. 35) are representative examples of inverse crown complexes." " Those complexes are coined inverse crowns in view of their topological but inverse relation to conventional crown ethers in... [Pg.28]

The homoleptic sodium magnesiate 27 (Fig. 20) represents the first example of a structurally characterized solvent-free tris-alkyl version reported in the frterature. Complex 27 exists as a polymeric ate— prepared by a co-complexation approach by mixing the monometaUic alkyls [NaCH2SiMe3] and [Mg(CH2SiMe3)] in an -hexane/toluene solvent... [Pg.14]

Francos J, Fleming BJ, Garcia-Alvarez P, et al. Complexity in seemingly simple sodium magnesiate systems. Dalton Trans. 2014 43(38) 14424—14431. [Pg.44]

See other pages where Sodium Magnesiate Complexes is mentioned: [Pg.194]    [Pg.14]    [Pg.14]    [Pg.16]    [Pg.24]    [Pg.31]    [Pg.146]    [Pg.194]    [Pg.14]    [Pg.14]    [Pg.16]    [Pg.24]    [Pg.31]    [Pg.146]    [Pg.110]    [Pg.14]    [Pg.15]    [Pg.19]    [Pg.25]    [Pg.27]    [Pg.27]    [Pg.29]    [Pg.134]    [Pg.131]    [Pg.126]   


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