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Sodium hexamethyl disilazide

Sodium hexamethyl disilazide (NaHMDS) is a strong non-nucleophilic base. [Pg.125]

Reductive elimination of sugar tosyl hydrazones using sodium hexamethyl-disilazide/LAH provides a route to various homochiral dioxolanes. Thus, D-xylose, D-arabinose and D-xylose derivatives 71-73 were converted to isopro-pylidene acetals 74-76, while D-xylose derivatives 77 and 78 provided 6-membered acetals 79 and 80, respectively. ... [Pg.361]

See other pages where Sodium hexamethyl disilazide is mentioned: [Pg.106]    [Pg.178]    [Pg.113]   


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2,2 ,4,4 ,5,5 -Hexamethyl

Hexamethyl disilazides

Sodium hexamethyl disilazide NaHMDS)

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