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Sodium complexes TMEDA ligands

Scheme 2.5 Decomposition of tmeda ligands to enable the formation of high nuclearity sodium amide complexes ... Scheme 2.5 Decomposition of tmeda ligands to enable the formation of high nuclearity sodium amide complexes ...
The crystal structure of the red triphenylmethylsodium TMEDA complex (compound XVI in Fig. 3), published by Weiss and Koster (41), resembles that of the red triphenylmethyllithium-TMEDA complex (42) and can be described as a n complex between a triphenylmethyl carbanion with an sp2-hybridized central carbon atom and a sodium cation coordinated to the bidentade ligand TMEDA. The sodium atom has close contacts to several carbon atoms of the triphenylmethyl ligand, which possesses twisted phenyl groups. An additional short distance exists between sodium and a p-C (phenyl) atom of a neighboring n system. [Pg.224]

See other pages where Sodium complexes TMEDA ligands is mentioned: [Pg.19]    [Pg.22]    [Pg.10]    [Pg.15]    [Pg.25]    [Pg.25]    [Pg.214]    [Pg.23]    [Pg.90]    [Pg.39]    [Pg.1052]    [Pg.167]    [Pg.168]    [Pg.302]    [Pg.203]    [Pg.75]    [Pg.136]    [Pg.23]    [Pg.431]    [Pg.398]    [Pg.186]    [Pg.150]   
See also in sourсe #XX -- [ Pg.31 , Pg.32 ]



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