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SKIE solvent kinetic isotope

A solvent kinetic isotope effect (SKIE) of 0.44 from solvolysis in CD3CN-H2O versus CD3CN-D2O mixtures was in line with predicted values for the protonation-dissociation mechanism for which the SKIE should be between 0.48 and 0.33 (Figure 18a... [Pg.878]

Solvolysis rate constants of 5-nitro-2-furoyl chloride in 27 different solvents were well correlated with the extended Grunwald-Winstein equation, with sensitivity values of 1.20 0.05 and 0.37 0.02 for I and m, respectively. These data, the range of values found for A// and AS, and the solvent kinetic isotope effect (SKIE, MeOH MeOD) of 2.65 were in accord with an 5 2 mechanism. ... [Pg.72]

See other pages where SKIE solvent kinetic isotope is mentioned: [Pg.1033]    [Pg.71]    [Pg.5]   


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