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Six-Coordinate Aluminum Cations Based on Salen Ligands

SIX-COORDINATE ALUMINUM CATIONS BASED ON SALEN LIGANDS [Pg.14]

Submitted by SAMEER SAHASRABUDHE, BURL C. YEARWOOD, and DAVID A. ATWOOD [Pg.14]

All manipulations are conducted by using appropriate inert-atmosphere techniques. Toluene and THF are refluxed over sodium benzophenone and MeOH over Mg and then distilled prior to use. The ligands SalenH2 and Salen BuH2 were synthesized as described previously. Dimethylaluminum chloride is available from Aldrich Chemical Co. [Pg.14]

Six-Coordinate Aluminum Cations Based on Salen Ligands... [Pg.15]

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Aluminum cationic

Aluminum coordination

Aluminum salen

Base cation

Cationic coordination

Ligand coordination

Ligand-based

Ligands cationic

Salen

Salen ligands

Salens

Six coordination