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Singlets, diazocarbonyl compounds

The singlet form of carbenes substituted with a carbonyl group is much lower in energy than the triplet, so the photolysis of a-diazocarbonyl compounds gives singlet carbenes. The photo-Wolff rearrangement (Chapter 2) of a-diazoketones occurs upon photolysis of these compounds. [Pg.264]

See other pages where Singlets, diazocarbonyl compounds is mentioned: [Pg.25]    [Pg.18]    [Pg.436]    [Pg.1049]    [Pg.436]    [Pg.423]    [Pg.108]    [Pg.751]    [Pg.274]    [Pg.751]    [Pg.409]    [Pg.1823]   
See also in sourсe #XX -- [ Pg.4 ]



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