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Singlet oxygen reactivity

Mechanism of Photooxidation of Spirooxazines Singlet-Oxygen Reactivity... [Pg.124]

Hence either the reactive singlet oxygen molecule or oxygen atoms are produced either of these may initiate radical chain processes that lead to degradation. [Pg.122]

Keywords Cycloadditions, Chemical orbital theory. Donor-acceptor interaction. Electron delocalization band. Electron transfer band, Erontier orbital. Mechanistic spectrum, NAD(P)H reactions. Orbital amplitude. Orbital interaction. Orbital phase. Pseudoexcitation band. Quasi-intermediate, Reactivity, Selectivity, Singlet oxygen. Surface reactions... [Pg.24]

Katsumura, Kitaura and their coworkers [74] found and discussed the high reactivity of vinylic vs allylic hydrogen in the photosensitized reactions of twisted 1,3-dienes in terms of the interaction in the perepoxide structure. Yoshioka and coworkers [75] investigated the effects of solvent polarity on the product distribution in the reaction of singlet oxygen with enolic tautomers of 1,3-diketones and discussed the role of the perepoxide intermediate or the perepoxide-Uke transition state to explain their results. A recent review of the ene reactions of was based on the significant intervention of the perepoxide structure [76], which can be taken as a quasi-intermediate. [Pg.38]

Michaeli, A. Feitelson, J. (1994). Reactivity of singlet oxygen toward amino acids and peptides. Photochemistry and Photobiology, Vol.59, No.3, (March 1994), pp. 284-289, ISSN 0031-8655. [Pg.23]

Illuminated chlorophyll molecules can form excitation states which are able to transfer energy on to the oxygen molecule, raising it from its ground state to the more reactive excited state known as singlet oxygen. [Pg.120]

Although this mechanism could explain the inertness of di-t-butyl sulphide towards oxidation due to the absence of a-hydrogen atoms, it was later ruled out by Tezuka and coworkers They found that diphenyl sulphoxide was also formed when diphenyl sulphide was photolyzed in the presence of oxygen in methylene chloride or in benzene as a solvent. This implies that a-hydrogen is not necessary for the formation of the sulphoxide. It was proposed that a possible reactive intermediate arising from the excited complex 64 would be either a singlet oxygen, a pair of superoxide anion radical and the cation radical of sulphide 68 or zwitterionic and/or biradical species such as 69 or 70 (equation 35). [Pg.252]

The reactivity order of alkenes is that expected for attack by an electrophilic reagent. Reactivity increases with the number of alkyl substituents.163 Terminal alkenes are relatively inert. The reaction has a low AHl and relative reactivity is dominated by entropic factors.164 Steric effects govern the direction of approach of the oxygen, so the hydroperoxy group is usually introduced on the less hindered face of the double bond. A key mechanistic issue in singlet oxygen oxidations is whether it is a concerted process or involves an intermediate formulated as a pcrcpoxide. Most of the available evidence points to the perepoxide mechanism.165... [Pg.1119]


See other pages where Singlet oxygen reactivity is mentioned: [Pg.313]    [Pg.364]    [Pg.209]    [Pg.313]    [Pg.364]    [Pg.209]    [Pg.240]    [Pg.203]    [Pg.494]    [Pg.495]    [Pg.114]    [Pg.22]    [Pg.437]    [Pg.174]    [Pg.76]    [Pg.656]    [Pg.281]    [Pg.614]    [Pg.60]    [Pg.290]    [Pg.548]    [Pg.252]    [Pg.122]    [Pg.921]    [Pg.40]    [Pg.120]    [Pg.120]    [Pg.121]    [Pg.42]    [Pg.56]    [Pg.58]    [Pg.178]    [Pg.234]    [Pg.176]    [Pg.176]    [Pg.2]    [Pg.43]    [Pg.127]    [Pg.131]    [Pg.205]    [Pg.451]    [Pg.187]   
See also in sourсe #XX -- [ Pg.124 ]




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