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Simple Derivation of the Dyson Equation

If it is assumed that we work again with a nonorthogonal basis set Xr), then the unperturbed problem assumes the form [Pg.115]

The Green matrix of this system can be given, by analogy with expression (4.37), as [Pg.115]

The expression (4.40) finally yields the Dyson equation from (4.44) in the form [Pg.116]

Effect of Side-Chain Disorder on the Eiectronic Structure of Proteins [Pg.117]

In the calculations of the electronic structure of these polypeptides, we applied the all-valence electron MINDO crystal-orbital method in its MINDO/3 parametrization. The calculations involved atomic coordinates corresponding to the antiparallel-) -pleated-sheet structure of Pauling and Corey S hence we had a combined symmetry operation in the case of poly( y) each gly unit was obtained in this polymer from its neighboring one by a translation along the helical axis through 3.25 A and by a simultaneous 180° rotation around it. In order to preserve the cyclic property of the Fock hypermatrix of the whole polymer (which is [Pg.117]


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