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Simmons-Smith cydopropanation

Tab. 3.6 Tartrate reagent modification in the Simmons-Smith cydopropanation... Tab. 3.6 Tartrate reagent modification in the Simmons-Smith cydopropanation...
SHAFIPLESS Asymmetne epoxidation 343 SHARPLESS Asymmetric d tydroxylalion 344 SHERAOSKY Rearrangement 345 SHESTAKOV Hydrazine synthesis 346 SIEGRIST Stilbene synthesis 347 SIMMONS - SMITH Cydopropane synthesis 348... [Pg.455]

Dichlorocarbene and the Simmons-Smith reagent react stereospecifically with alkenes to give cydopropanes. [Pg.625]

Cydopropanation of cyclohexene using the Simmons Smith Reageni ... [Pg.350]

Hydrozirconation of functionalized alkyne 8 in CH2C32 with the Schwartz reagent followed by in situ transmetallation to Me2Zn and addition of N-diphenyl-phosphinoylimine 15 provides the functionalized trans-aminocydopropane 16 in 60% yield [15]. The cydopropane formation can be rationalized by the formation of a transient zinc-carbenoid species from CH2CI2, which subjected the intermediate allylic amine derivative to an efficient Simmons-Smith-type cydopropanation. [Pg.509]

See other pages where Simmons-Smith cydopropanation is mentioned: [Pg.116]    [Pg.119]    [Pg.316]    [Pg.909]    [Pg.116]    [Pg.119]    [Pg.316]    [Pg.909]    [Pg.116]    [Pg.436]    [Pg.622]   
See also in sourсe #XX -- [ Pg.251 ]



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Cydopropanation

Cydopropanations

Cydopropane

Cydopropanes

Simmons-Smith

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