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Silylated fullerene 1,16-adduct

As for the C-C bond formation with fullerene, the pho-toinduced electron transfer with ketene silyl acetal (KSA) was reported. For example, KSA derived from ethyl acetates generated fullerene-acetates quantitatively upon photoirradiation in benzene (Scheme 4) [66]. Their reactivities to form Cgg-adducts are studied on the basis of the oxidation potentials of the KSA, indicating adduct formation via electron transfer with triplet excited Cgg. Furthermore, Danishefsky s diene, which is a vinylogue of KSA, formed [4 -I- 2] cycloadducts of Qg by the Diels-Alder reaction (Scheme 5)... [Pg.7]

See other pages where Silylated fullerene 1,16-adduct is mentioned: [Pg.202]    [Pg.53]    [Pg.199]    [Pg.1301]    [Pg.717]    [Pg.1531]    [Pg.75]    [Pg.90]    [Pg.93]    [Pg.1531]    [Pg.215]    [Pg.1301]    [Pg.439]   
See also in sourсe #XX -- [ Pg.201 , Pg.202 ]



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Silylated fullerene

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