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Silyl-transition metal complexes anionic derivatives

Early transition-metal silyl compounds have received much less attention, largely due to the fact that general, straightforward synthetic routes have not been available. Syntheses based on oxidative additions are less applicable, given the more electropositive character of the early metals. Particularly for d° silyl complexes, most syntheses are based on nucleophilic displacement of halide by a silyl anion reagent, usually an alkali metal derivative. [Pg.1424]


See other pages where Silyl-transition metal complexes anionic derivatives is mentioned: [Pg.2054]    [Pg.132]    [Pg.4432]    [Pg.285]    [Pg.4431]    [Pg.2054]    [Pg.185]    [Pg.37]    [Pg.3]    [Pg.37]    [Pg.236]    [Pg.150]    [Pg.132]   
See also in sourсe #XX -- [ Pg.295 ]




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Anion complexation

Anion, , complex

Complex anionic

Complexes silyls

Derivatives complexation

Metal anionic

Metal anions

Metal silyl

Metal silyl anions

Metallic derivates

Silyl complexes

Silyl derivatives

Silyl-transition metal complexes

Silyls metal

Transition metal anions

Transition-metal complex anions

Transition-metal derivatives

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