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Silyl dienol ethers cross-conjugated

Lewis acid catalyzed alkylations of cross-conjugated silyl dienol ethers provide routes to a -alkylated ketones. A short synthesis of the sesquiterpene ( )-ar-turmerone has been accomplished using the cross-conjugated TMS dienol ether of mesityl oxide (equation 9). ... [Pg.28]


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Conjugation cross

Cross-conjugated

Dienol ethers

Dienolate

Dienolates

Dienols

Ether conjugate

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