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Silyl anions from silicon hydrides

The mechanism involves the preferential attack of the hydride on the less hindered silicon with formation of a pentacoordinated anionic species which collapses to give an a-silyl carbanion intermediate and SiH4 gas. The a-silyl carbanion may then take up a hydrogen from the hydrogen source (e.g., silane or solvent) to yield 7 or may lose... [Pg.157]

See other pages where Silyl anions from silicon hydrides is mentioned: [Pg.371]    [Pg.302]    [Pg.156]    [Pg.302]    [Pg.496]    [Pg.1443]    [Pg.75]    [Pg.260]    [Pg.31]    [Pg.558]    [Pg.2054]    [Pg.2072]    [Pg.189]    [Pg.372]    [Pg.101]    [Pg.45]    [Pg.558]    [Pg.2054]    [Pg.2072]   
See also in sourсe #XX -- [ Pg.4 , Pg.4 , Pg.5 , Pg.5 ]

See also in sourсe #XX -- [ Pg.4 , Pg.4 , Pg.5 , Pg.5 , Pg.11 ]



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Silicon hydrides

Silicon silyl

Silicon silyl anions

Silyl hydrides

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