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Silver® chalcogenide complexes

Tributylphosphine sulfide has been used as a co-catalyst with dicobalt octacarbonyl for the Pawson-Khand reaction. Thermolysis of a mixture of cadmium chloride and trioctylphosphine sulfide at 250 °C has been used as a route to the formation of nanocrystalline cadmium sulfide." A complex of triphenylphosphine sulfide with a silver-tungsten-iodine acceptor has been characterised by X-ray studies. Ferrocenylphosphine chalcogenides have attracted considerable interest as ligands. Complexes of the monophosphino-phosphine sulfide (269) with rhodium have been characterised." The disulfide (270) forms complexes with both gold(i) and gold(iii) acceptors," and a silver(i) complex of the diselenide (271) has been prepared. ... [Pg.37]

Phosphine Chalcogenides as Ligands. - The enhanced stability provided by two triphenylphosphine oxide ligands has enabled the first crystal structure analysis of a non-haem-di-iron-dioxygen adduct. Complexes of the bis(phosphine oxide) (213 Z=0) with copper(I) and copper(II), and of the related disulfide (213 Z=S) with gold(I) and silver(I), have been characterised. [Pg.30]

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See also in sourсe #XX -- [ Pg.69 ]



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