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Silicon-tethered ene cyclization

Scheme 10-106 Silicon-tethered ene cyclization is highly stereoselective. Scheme 10-106 Silicon-tethered ene cyclization is highly stereoselective.
Silicon-tethered Ene Reactions. Silicon-tethered cyclization reactions have been widely utilized because of the ease of formation and removal of the temporary silicon tether and the ability of organosilicon compounds to tolerate many commonly used organic transformations. One example involves the ene reaction of a-(prenyl)dialkylsilyloxy aldehydes (eq 13). A 1,2-diol (39) can... [Pg.153]


See other pages where Silicon-tethered ene cyclization is mentioned: [Pg.89]    [Pg.361]    [Pg.363]    [Pg.89]    [Pg.361]    [Pg.363]   
See also in sourсe #XX -- [ Pg.362 , Pg.363 ]




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Cyclization silicon-tethered

Ene cyclization

Silicon tethers

Tether

Tethering

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