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Silicon-29 NMR spectroscopy

Higher resolution aluminium-27 and silicon-29 NMR spectroscopy of glasses and crystals along the join calcium magnesium silicate-calcium aluminium silicate (CaMgSijOj-CaAljSiO,). American Mineralogist, 71, 705-11. [Pg.183]

The most recent comprehensive review focused primarily on the reactivity aspects of hypervalent silicon complexes6, while the latest review covers only silicon-oxygen coordination7. The present chapter focuses on synthesis and structure, silicon-29 NMR spectroscopy, and on the nonrigidity of hypervalent silicon compounds and the resulting kinetic and stereochemical studies. [Pg.1340]

Coleman, B. (1983). Applications of silicon-29 NMR spectroscopy. In P. Laszlo, Ed. NMR Newly Accessible Nuclear, 2 197-228. New York Academic. [Pg.332]

Figure 15.21. CP/MAS spectra l3C inp-dimethoxybenzene (note splitting induced in ortho carbons due to the asymmetry of the methoxy group), 29Si in poly-[dimethy lsiloxane) (PDMS), and 31P in bone mineral [roughly equivalent to Ca50H(P04)3]. (29Si spectrum reprinted with permission from Beshah K, Mark JE, Himstedt A, Ackerman JL. Characterization of PDMS model junctions and networks by solution and solid state silicon-29 NMR spectroscopy. J Polymer Sci B Polymer Phys. 1986 24 1207-1225. Copyright 1986 John Wiley Sons.)... Figure 15.21. CP/MAS spectra l3C inp-dimethoxybenzene (note splitting induced in ortho carbons due to the asymmetry of the methoxy group), 29Si in poly-[dimethy lsiloxane) (PDMS), and 31P in bone mineral [roughly equivalent to Ca50H(P04)3]. (29Si spectrum reprinted with permission from Beshah K, Mark JE, Himstedt A, Ackerman JL. Characterization of PDMS model junctions and networks by solution and solid state silicon-29 NMR spectroscopy. J Polymer Sci B Polymer Phys. 1986 24 1207-1225. Copyright 1986 John Wiley Sons.)...
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Silicon NMR

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