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Silicon-centered anion radicals

Silicon-centered anion radicals from polysilanes... [Pg.195]

This chapter will concentrate on the chemistry of metal-14-centered anions (Ge, Sn, Pb). These compounds and their silyl analogues are ionic or polarized alkaline and alkaline earth metal-14 compounds, as well as delocalized molecules such as metalloles. Ammonium metallates Mi4 R4N+ or metal-14-centered anion radicals are also considered. The subject was explored during the 1960s and 1970s and thoroughly reviewed in 1982 and 1995 in Comprehensive Organometallic Chemistry, Vols. I and and for silicon species in a previous volume of this series . By that time the main routes to metal-14 anions were known. Since then, the subject has been developed in the topics of particular syntheses, stabilization using steric hindrance, electronic effects and complexation, spectroscopic and structural analyses "... [Pg.655]

Silicon-, Germanium-, and Tin-Centered Cations, Radicals, and Anions ... [Pg.47]

SILICON-, GERMANIUM-, AND TIN-CENTERED CATIONS, RADICALS, AND ANIONS... [Pg.48]

See other pages where Silicon-centered anion radicals is mentioned: [Pg.193]    [Pg.193]    [Pg.194]    [Pg.193]    [Pg.193]    [Pg.194]    [Pg.655]    [Pg.418]    [Pg.86]   


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Silicon-centered radicals

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