Silanetriols with bulky alkyl substituent

Silanetriols With Bulky Alkyl Substituent 1,1 -Trimethylpropylsilanetriol 401... 

SILANETRIOLS WITH BULKY ALKYL SUBSTITUENT 1,1,2-TRIMETHYLPROPYLSILANETRIOL... 

Similarly to those with bulky alkyl substituents, silanetriols with bulky aryl groups can be synthesized and isolated without problems. Thus 2,4,6-triisopropylphenylsilanetriol, or TipSi(OH)3, was readily prepared by the hydrolysis of TipSiCla in 70% yield (1). Although with bulky Tip group, this compound showed no restricted rotation and and C-NMR spectra exhibited sharp... 

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